Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives
نویسندگان
چکیده
This paper describes a simple route to enantiomerically enriched [2.2]paracyclophane-4-thiol via the stereospecific introduction of a chiral sulfoxide to the [2.2]paracyclophane skeleton. The first synthesis of an enantiomerically enriched planar chiral benzothiazole is also reported.
منابع مشابه
[2.2]Paracyclophane derivatives containing tetrathiafulvalene moieties
The synthesis of [2.2]paracyclophane derivatives containing tetrathiafulvalene units has been accomplished by the coupling reaction of 4-([2.2]paracyclophan-4-yl)-1,3-dithiol-2-thione in the presence of trimethylphosphite. The 1,3-dithiol-2-thione derivative was in turn synthesized by the regioselective bromination of 4-acetyl[2.2]paracyclophane, then through the corresponding dithiocarbamates ...
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عنوان ژورنال:
دوره 5 شماره
صفحات -
تاریخ انتشار 2009